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	<title>MTL Annual Research Report 2012 &#187; zhihong liu</title>
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		<title>Technology Development for GaN and Si Integration</title>
		<link>http://www-mtl.mit.edu/wpmu/ar2012/technology-development-for-gan-and-si-integration/</link>
		<comments>http://www-mtl.mit.edu/wpmu/ar2012/technology-development-for-gan-and-si-integration/#comments</comments>
		<pubDate>Wed, 18 Jul 2012 22:27:17 +0000</pubDate>
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				<category><![CDATA[Electronic Devices]]></category>
		<category><![CDATA[gallium nitride]]></category>
		<category><![CDATA[tomas palacios]]></category>
		<category><![CDATA[zhihong liu]]></category>

		<guid isPermaLink="false">http://www-mtl.mit.edu/wpmu/ar2012/?p=5811</guid>
		<description><![CDATA[GaN is an excellent material to be used in high-power, high-frequency and high-temperature applications due to its wide band gap,...]]></description>
				<content:encoded><![CDATA[<div class="page-restrict-output"><p>GaN is an excellent material to be used in high-power, high-frequency and high-temperature applications due to its wide band gap, high saturation velocity, etc. The monolithic integration of GaN power and/or high frequency devices with Si CMOS digital ICs would enable a new level of circuit design flexibility<sup> [<a href="http://www-mtl.mit.edu/wpmu/ar2012/technology-development-for-gan-and-si-integration/#footnote_0_5811" id="identifier_0_5811" class="footnote-link footnote-identifier-link" title="H. S. Lee, K. Ryu, M. Sun, and T. Palacios, &ldquo;Wafer-level heterogeneous integration of GaN HEMTs on Si (100) MOSFETs,&rdquo; IEEE Electron Device Letters, vol. 33, no. 2, pp. 200-202, Feb. 2012.">1</a>] </sup>. However, typically the GaN device fabrication uses different process technologies from the standard CMOS technologies in Si foundries, such as the Au-contained ohmic process. To realize the target of GaN and Si CMOS integration, Si-CMOS compatible process technologies need to be developed. For the first step, we endeavor to find an Au-free ohmic contact recipe with low contact resistance and smooth metal surface.</p>
<p>The samples we used in this work have a 3-nm GaN cap, a 20-nm unintentionally doped AlGaN barrier layer, and a GaN buffer layer grown on a 6-inch Si wafer. Mesa isolation was realized using ICP systems with Cl<sub>2</sub>/BCl<sub>3</sub> gases. For the ohmic contact, we tried different metal schemes including Ti/Al, Ti/Al/Ti, Ti/Al/Pt, Ti/Al/Ni/Pt, Ti/Ge/Ti/Al/Ni/Pt, Si/Ti/Al/Ti/Ta, Mo/Al/Mo/Ti, Ta/Al/Ta, Ta/Al/Ni/Ta, etc, with different annealing temperatures varying from 500°C to 975°C using rapid thermal annealing (RTA) in N<sub>2</sub> ambience. We also tried to include a shallow recess using low etch-rate SiCl<sub>4</sub> plasma etch in an ICP system to improve the ohmic contact. Among these recipes, the metal scheme of Ti/Al/Ni/Pt is found to give a relatively low contact resistance with very good metal surface. Lower ohmic contact resistance values together with a smooth metal surface can be obtained if a 20-30-nm recess is added.</p>
<p>Figure 1 shows the optical pictures of the ohmic metal surface after RTA for 30 s for metal schemes of Ti/Al/Ni/Au, Ti/Al/Ni/Pt, and Ti/Al/Ni/Pt with recess. The Au-contained recipe shows a very rough surface even it is annealed at a relatively low temperature of 800°C. The intermixing of Al and Au and the formation of viscous AlAu<sub>4</sub> phase are believed to result in the rough surface<sup> [<a href="http://www-mtl.mit.edu/wpmu/ar2012/technology-development-for-gan-and-si-integration/#footnote_1_5811" id="identifier_1_5811" class="footnote-link footnote-identifier-link" title="A. N. Bright, P. J. Thomas, M. Weyland, D. M. Tricker, C. J. Humphreys, and R. Davies, &ldquo;Correlation of contact resistance with microstructure for Au/Ni/Al/Ti/AlGaN/GaN ohmic contacts using transmission electron microscopy,&rdquo; Journal of Appl. Phys., vol. 89, no. 6, pp. 3143-3150, Mar. 2001.">2</a>] </sup>. Without Au, the metal surface of Ti/Al/Ni/Pt is very smooth even it is annealed at a much high temperature up to 950°C. The recess of 20 nm (and 30 nm, not shown here) has no obvious effect on the metal surface after annealing. Figure 2 shows the typical contact resistance (<em>R</em><sub>C</sub>) values measured using the transition length method (TLM). A low <em>R</em><sub>C</sub> of around 0.45 Ω-mm can be obtained for the normal Ti/Al/Ni/Au recipe. The <em>R</em><sub>C</sub> value of Ti/Al/Ni/Pt metal is higher (~2.0 Ω-mm), and it can decrease to 1.6Ω-mm with the recess of 20 nm. In the future, more work needs to be carried out to further lower the <em>R</em><sub>C </sub>and optimize the Au-free ohmic contact recipes.</p>

<a href='http://www-mtl.mit.edu/wpmu/ar2012/technology-development-for-gan-and-si-integration/liu_integration_01/' title='liu_integration_01'><img width="300" height="162" src="http://www-mtl.mit.edu/wpmu/ar2012/files/2012/07/liu_integration_01-300x162.png" class="attachment-medium" alt="Figure 1" /></a>
<a href='http://www-mtl.mit.edu/wpmu/ar2012/technology-development-for-gan-and-si-integration/liu_integration_02/' title='liu_integration_02'><img width="300" height="240" src="http://www-mtl.mit.edu/wpmu/ar2012/files/2012/07/liu_integration_02-300x240.png" class="attachment-medium" alt="Figure 2" /></a>

<ol class="footnotes"><li id="footnote_0_5811" class="footnote">H. S. Lee, K. Ryu, M. Sun, and T. Palacios, “Wafer-level heterogeneous integration of GaN HEMTs on Si (100) MOSFETs,” <em>IEEE Electron Device Letters,</em> vol. 33, no. 2, pp. 200-202, Feb. 2012.</li><li id="footnote_1_5811" class="footnote">A. N. Bright, P. J. Thomas, M. Weyland, D. M. Tricker, C. J. Humphreys, and R. Davies, “Correlation of contact resistance with microstructure for Au/Ni/Al/Ti/AlGaN/GaN ohmic contacts using<strong> </strong>transmission electron microscopy,” <em>Journal of Appl. Phys.</em>, vol. 89, no. 6, pp. 3143-3150, Mar. 2001.</li></ol></div>]]></content:encoded>
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